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TiO2 thin films sensitization with natural dyes extracted from Bactris guineensis for photocatalytic applications: Experimental and DFT study

dc.contributor.authorDiaz-Uribe, Carlos
dc.contributor.otherVallejo, William
dc.contributor.otherRomero, Eduardo
dc.contributor.otherVillareal, M.
dc.contributor.otherPadilla, M.
dc.contributor.otherHazbun, N.
dc.contributor.otherMunoz-Acevedo, Amner
dc.contributor.otherSchott, Eduardo
dc.contributor.otherZarate, Ximena
dc.date.accessioned2022-11-15T21:22:26Z
dc.date.available2022-11-15T21:22:26Z
dc.date.issued2020-03-11
dc.date.submitted2019-11-26
dc.identifier.urihttps://hdl.handle.net/20.500.12834/984
dc.description.abstractTiO2 thin films, sensitized by an anthocyanins-rich extract of a common species found in the Colombian Caribbean region (Bactris guineensis fruits), were used for the photocatalytic degradation of methylene blue. The sensitization process was verified by diffuse reflectance spectroscopy (DRS). The qualitative and quantitative analyses of the anthocyanins were carried out using highperformance liquid chromatography with photodiode array detection (HPLC-DAD), which provided the total content anthocyanin equivalent to delphinidin chloride (TAEDC) per mL of the extract, of 10.0 ± 0.8 mg TAEDC/mL. Here, three main anthocyanins were identified, being cyanidin-3-rutinoside the most abundant constituent (ca. 76%). The interaction of the dyes with a TiO2 slab model and their adsorption energies were determined through computational simulations. In addition, the molecular modelling evidenced that the sensitization of the semiconductor improved the light absorption in the visible range of the spectrum. As a final point, the photocatalytic test showed that the photocatalytic activity increased 26% for TiO2/B. guineensis thin films under visible radiation respect to bare TiO2.spa
dc.format.mimetypeapplication/pdfspa
dc.language.isoengspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.sourceElsevier B.V.spa
dc.titleTiO2 thin films sensitization with natural dyes extracted from Bactris guineensis for photocatalytic applications: Experimental and DFT studyspa
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datacite.rightshttp://purl.org/coar/access_right/c_abf2spa
oaire.resourcetypehttp://purl.org/coar/resource_type/c_6501spa
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
dc.audiencePúblico generalspa
dc.identifier.doi10.1016/j.jscs.2020.03.004
dc.identifier.instnameUniversidad del Atlánticospa
dc.identifier.reponameRepositorio Universidad del Atlánticospa
dc.rights.ccAttribution-NonCommercial 4.0 International*
dc.subject.keywordsTiO2; Natural sensitizer; Anthocyanin; DFTspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersionspa
dc.type.spaArtículospa
dc.publisher.placeBarranquillaspa
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessspa
dc.publisher.disciplineQuímicaspa
dc.publisher.sedeSede Nortespa


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