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Effects of Different Concentrations of Arsine on the Synthesis and Final Properties of Polypropylene

dc.contributor.authorHernández Fernández, Joaquín
dc.contributor.otherGuerra, Yoleima
dc.contributor.otherPuello Polo, Esneyder
dc.contributor.otherMarquez, Edgar
dc.coverage.spatialColombia
dc.date.accessioned2022-11-15T19:12:22Z
dc.date.available2022-11-15T19:12:22Z
dc.date.issued2022-07-31
dc.date.submitted2022-06-20
dc.identifier.citationHernández-Fernández, J.; Guerra, Y.; Puello-Polo, E.; Marquez, E. Effects of Different Concentrations of Arsine on the Synthesis and Final Properties of Polypropylene. Polymers 2022, 14, 3123. https:// doi.org/10.3390/polym14153123spa
dc.identifier.urihttps://hdl.handle.net/20.500.12834/772
dc.description.abstractThis article studies the effects of arsine on the synthesis and thermal degradation of 4 samples of virgin polypropylene (PP-virgin) and proposes reaction mechanisms that allow understanding of its behaviour. Different points are monitored during the polypropylene synthesis to perform TGA, DSC, FT-IR, RDX, and MFI analyses later. The content of AsH3 in polypropylene varies between 0.05 and 4.73 ppm, and of arsenic in virgin PP residues between 0.001 and 4.32 ppm for PP0 and PP10, increasing in fluidity index from 3.0 to 24.51. The origin of thermo-oxidative degradation is explained by the reaction mechanisms of the Molecule AsH3 with the active titanium center of the ZN catalyst and the subsequent oxidation to form radical complexes. OO-AsH-TiCl4-MgCl2 and (OO-as-OO)2 -TiCl4-MgCl2, which, by radical reactions, give rise to the formation of functional groups aldehyde, ketone, alcohol, carboxylic acid, CO, CO2, PP-Polyol, PP-Polyether, and PP-Isopropylethers. These species caused the TG and DTG curves to increase degradation peaks in pp samples.spa
dc.format.mimetypeapplication/pdfspa
dc.language.isoengspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.sourcePolymersspa
dc.titleEffects of Different Concentrations of Arsine on the Synthesis and Final Properties of Polypropylenespa
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datacite.rightshttp://purl.org/coar/access_right/c_abf2spa
oaire.resourcetypehttp://purl.org/coar/resource_type/c_2df8fbb1spa
oaire.versionhttp://purl.org/coar/version/c_970fb48d4fbd8a85spa
dc.audiencePúblico generalspa
dc.identifier.doi10.3390/polym14153123
dc.identifier.instnameUniversidad del Atlánticospa
dc.identifier.reponameRepositorio Universidad del Atlánticospa
dc.rights.ccAttribution-NonCommercial 4.0 International*
dc.subject.keywordsarsinespa
dc.subject.keywordsligandsspa
dc.subject.keywordspolypropylenespa
dc.subject.keywordscatalystspa
dc.subject.keywordsdegradationspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.hasVersioninfo:eu-repo/semantics/publishedVersionspa
dc.type.spaArtículospa
dc.publisher.placeBarranquillaspa
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessspa
dc.publisher.disciplineQuímicaspa
dc.publisher.sedeSede Nortespa


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