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Evaluation of the Zinc Sulfate Catalytic Effect in Empty Fruit Bunches Pyrolysis

dc.contributor.authorSuárez Useche, María Alejandra
dc.contributor.otherCastillo Santiago, York
dc.contributor.otherB. Restrepo, Juan
dc.contributor.otherAlbis Arrieta, Alberto Ricardo
dc.contributor.otherAgámez Salgado, Karen Patricia
dc.coverage.spatialColombia
dc.date.accessioned2022-11-15T19:10:46Z
dc.date.available2022-11-15T19:10:46Z
dc.date.issued2022-09-02
dc.date.submitted2022-07-19
dc.identifier.citationSuárez Useche, M.A.; Castillo Santiago, Y.; Restrepo, J.B.; Albis Arrieta, A.R.; Agámez Salgado, K.P. Evaluation of the Zinc Sulfate Catalytic Effect in Empty Fruit Bunches Pyrolysis. Processes 2022, 10, 1748. https://doi.org/10.3390/ pr10091748spa
dc.identifier.urihttps://hdl.handle.net/20.500.12834/765
dc.description.abstractThe effect of zinc sulfate as a catalyst on the pyrolysis of empty fruit bunches (EFB) from oil palm was assessed. Thus, a thermo-gravimetric analyzer coupled with a Fourier transform infrared spectroscopy (TG-FTIR) was used, while the percentage of catalyst varied between 0 wt% and 3 wt% at different heating rates (10, 30, and 50 K/min). The kinetic parameters (activation energy, pre-exponential factor, and reaction order) and activation energy distribution were calculated using three kinetic models. The thermogravimetric curves for the EFB pyrolysis showed three prominent peaks in which the maximum mass loss rate was mainly due to cellulose and lignin pyrolysis. On the other hand, FTIR analysis indicated that the main gaseous products were CO2, CO, H2O, CH4, NH3, acids, and aldehydes (CH3COOH). The samples with 2 wt% of catalyst presented higher activation energies in pseudo reactions 1 and 2, ranging between 181,500 kJ/mol–184,000 kJ/mol and 165,200 kJ/mol–165,600 kJ/mol, respectively. It was highlighted that the first pseudo reaction with an activation energy range between 179,500 kJ/mol and 184,000 kJ/mol mainly contributes to the cellulose pyrolysis, and the second pseudo reaction (165,200 kJ/mol–165,600 kJ/mol) could be ascribed to the hemicellulose pyrolysis.spa
dc.format.mimetypeapplication/pdfspa
dc.language.isoengspa
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/*
dc.sourceProcessesspa
dc.titleEvaluation of the Zinc Sulfate Catalytic Effect in Empty Fruit Bunches Pyrolysisspa
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datacite.rightshttp://purl.org/coar/access_right/c_abf2spa
oaire.resourcetypehttp://purl.org/coar/resource_type/c_2df8fbb1spa
oaire.versionhttp://purl.org/coar/version/c_b1a7d7d4d402bccespa
dc.audiencePúblico generalspa
dc.identifier.doi10.3390/ pr10091748
dc.identifier.instnameUniversidad del Atlánticospa
dc.identifier.reponameRepositorio Universidad del Atlánticospa
dc.rights.ccAttribution-NonCommercial 4.0 International*
dc.subject.keywordspyrolysisspa
dc.subject.keywordsempty fruit bunchesspa
dc.subject.keywordsbiomassspa
dc.subject.keywordscatalystspa
dc.subject.keywordskineticsspa
dc.type.driverinfo:eu-repo/semantics/articlespa
dc.type.hasVersioninfo:eu-repo/semantics/draftspa
dc.type.spaArtículospa
dc.publisher.placeBarranquillaspa
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessspa
dc.publisher.disciplineIngeniería Mecánicaspa
dc.publisher.sedeSede Nortespa


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